- CAS 2695-47-8
- Purity 99%
Location：Home > Agrochemicals > 6-Bromo-1-hexene
6-Bromo-1-hexene Good Manufacturer supply High Quality 2695-47-8
- Molecular Formula: C6H11Br
- Molecular Weight: 163.057
- Appearance/Colour: colourless liquid
- Vapor Pressure: 4.36mmHg at 25°C
- Melting Point: -102.35°C (estimate)
- Refractive Index: n20/D 1.4652(lit.)
- Boiling Point: 153 °C at 760 mmHg
- Flash Point: 52.2 °C
- PSA： 0.00000
- Density: 1.2 g/cm3
- LogP: 2.73760
6-Bromo-1-hexene(Cas 2695-47-8) Usage
|
Synthesis Reference(s) |
Synthesis, p. 885, 1984 DOI: 10.1055/s-1984-31010 |
|
General Description |
Reaction of 6-bromo-1-hexene with Mg to form Grignard compounds has been investigated. The thermal chemistry of 6-bromo-1-hexene on Ni (100) surface has been studied under ultrahigh vacuum conditions by X-ray photoelectron spectroscopy and temperature-programmed desorption. |
InChI:InChI=1/C6H11Br/c1-2-3-4-5-6-7/h2H,1,3-6H2
2695-47-8 Relevant articles
-
Bodewitz,H.W.H.J. et al.
, p. 1053 - 1063 (1975)
-
Glycal approach to the synthesis of macrolide (-)-A26771B
Saidhareddy, Puli,Shaw, Arun K.
, p. 29114 - 29120 (2015)
A convergent total synthesis of a 16-mem...
A useful modification of the Kraus procedure1 for preparation of ω-bromo-1-alkenes by HMPA-promoted elimination of HBR from 1,ω-dibromoalkanes
Hoye,Van Veidhuizen,Vos,Zhao
, p. 1367 - 1371 (2001)
A reliable, reproducible, general, and d...
-
Butler,Price
, p. 1092,1094 (1959)
-
Mechanistic Insights into FLP-Catalyzed Iodoperfluoroalkylations
Spittler, Michael,Helmecke, Lucas,Czekelius, Constantin
supporting information, p. 458 - 468 (2018/09/06)
The frustrated Lewis pair-catalyzed iodo...
Synthesis and characterization of some atypical sphingoid bases
Saied, Essa M.,Le, Thuy Linh-Stella,Hornemann,Arenz, Christoph
supporting information, p. 4047 - 4057 (2018/06/30)
Sphingolipids are ubiquitous and abundan...
Aromatic Claisen Rearrangements of Benzyl Ketene Acetals: Conversion of Benzylic Alcohols to (ortho-Tolyl)acetates
Burns, Jed M.,Krenske, Elizabeth H.,McGeary, Ross P.
supporting information, p. 252 - 256 (2017/01/24)
Claisen rearrangements of benzyl vinyl e...
Simple and high yield access to octafunctional azido, amine and urea group bearing cubic spherosilicates
Sch?fer, Sandra,Kickelbick, Guido
supporting information, p. 221 - 226 (2016/12/28)
Spherosilicates and polyhedral oligomeri...
2695-47-8 Process route
-
-
629-03-8
1 ,6-dibromohexane
-
-
2695-47-8
6-Bromo-1-hexene
Conditions
| Conditions | Yield |
|---|---|
|
With
potassium tert-butylate;
In
tetrahydrofuran;
for 16h;
Inert atmosphere;
Reflux;
|
79%
|
|
With
N,N,N,N,N,N-hexamethylphosphoric triamide;
at 100 ℃;
under 100 Torr;
|
78%
|
|
With
N,N,N,N,N,N-hexamethylphosphoric triamide;
at 220 ℃;
for 0.0833333h;
|
54%
|
|
With
potassium hydroxide;
In
various solvent(s);
at 160 - 190 ℃;
for 4h;
under 80 Torr;
|
54%
|
|
With
18-crown-6 ether; potassium tert-butylate;
In
diethyl ether;
for 1h;
|
52%
|
|
With
N,N,N,N,N,N-hexamethylphosphoric triamide;
at 195 - 220 ℃;
for 0.0833333h;
|
51%
|
|
With
potassium hydroxide; 18-crown-6 ether;
In
various solvent(s);
at 205 ℃;
for 1h;
under 100 Torr;
|
50%
|
|
With
potassium hydroxide; 18-crown-6 ether;
In
various solvent(s);
at 250 ℃;
for 1h;
under 100 Torr;
|
50%
|
|
With
N,N,N,N,N,N-hexamethylphosphoric triamide;
at 200 ℃;
for 0.166667h;
under 750.06 Torr;
Irradiation;
|
49%
|
|
|
49%
|
|
With
N,N,N,N,N,N-hexamethylphosphoric triamide;
at 195 ℃;
|
|
|
With
N,N,N,N,N,N-hexamethylphosphoric triamide;
Heating;
|
|
|
With
potassium tert-butylate;
Inert atmosphere;
|
|
|
With
Hexamethylphosphorous triamide;
|
|
|
With
18-crown-6 ether; potassium tert-butylate;
In
diethyl ether;
|
-
-
821-41-0
5-Hexen-1-ol
-
-
2695-47-8
6-Bromo-1-hexene
Conditions
| Conditions | Yield |
|---|---|
|
With
pyridine; bromine; triphenylphosphine;
In
dichloromethane;
|
86%
|
|
With
pyridine; phosphorus tribromide;
In
diethyl ether;
|
83%
|
|
With
pyridine; bromine; triphenylphosphine;
In
benzene;
at 0 - 22 ℃;
for 5h;
|
80%
|
|
With
phosphorus tribromide;
In
N,N-dimethyl-formamide;
for 24h;
Ambient temperature;
|
80%
|
|
With
pyridine; phosphorus tribromide;
Ambient temperature;
|
79%
|
|
With
pyridine; phosphorus tribromide;
In
diethyl ether;
for 3h;
Heating;
|
75%
|
|
With
1H-imidazole; bromine; triphenylphosphine;
In
dichloromethane;
at 20 ℃;
for 0.416667h;
Inert atmosphere;
Cooling with ice;
|
60%
|
|
With
phosphorus tribromide;
In
diethyl ether;
at -78 - 25 ℃;
|
56%
|
|
With
pyridine; bromine; triphenylphosphine;
In
dichloromethane;
at 0 - 20 ℃;
for 20h;
|
49%
|
|
With
pyridine; phosphorus tribromide;
1.) -5 deg C, 30 min, 2.) RT, 2 h;
|
31%
|
|
With
phosphorus tribromide; N,N-dimethyl-formamide;
for 5h;
Cooling with ice;
|
26%
|
|
With
pyridine; phosphorus tribromide;
|
|
|
With
pyridine; phosphorus tribromide;
at 0 ℃;
|
|
|
With
pyridine; phosphorus tribromide;
|
|
|
Multistep reaction;
(i) TsCl, py, (ii) LiBr, acetone;
|
|
|
With
Pyridine hydrobromide;
for 2h;
Heating;
|
|
|
With
pyridine; phosphorus tribromide;
In
diethyl ether;
at -30 ℃;
for 2h;
|
|
|
With
carbon tetrabromide; triphenylphosphine;
In
dichloromethane;
|
|
|
Multi-step reaction
with
2
steps
1: 99 percent / pyridine / CH2
Cl2
/ 2 h / Ambient temperature
2: 67 percent / tetrabutylammonium bromide / tetrahydrofuran / Ambient temperature
With
pyridine; tetrabutylammomium bromide;
In
tetrahydrofuran; dichloromethane;
|
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